Saturday, 13 June 2020

Questions from Chemistry for Civils


CHEMICAL BONDING

1)With reference to ionic compounds, consider the following statements:  (2003)
i) Ionic compounds are insoluble in alcohol
ii) Ionic compounds in the solid state are good conductors of electricity
Which of these statements is/are correct?
a)      Only I      b) Only ii
c)       Both I and ii     d) Neither I nor ii                                                 Ans : only i
2) Which one of the following is paramagnetic in nature ?  (1997)
a) Iron   b) Hydrogen   c) Oxygen    d) Nitrogen                                    Ans: Oxygen

3) The basic reason for the extraordinary sparkle of a suitably cut diamond is that(1994)
a) It has a very high transparency
b) It has a very high refractive index
c) It is very hard
d) It has well-defined cleavage planes                                                    Ans: (b)

PHYSICAL CHEMISTRY
Structure of Atom:
1)      In an atom, the orded  of filling up of the orbitals is governed by :                         (2000)
a)      Aufbau principle    b) Heisenberg’s uncertainly principle
c)Hund’s rule   d) pauli’s exclusion principle        Ans:  ( c )

2)      The alpha particle carries two positive charges. Its mass is very nearly equal to that of    (1996)
a)      Two protons   b) an atom of helium  c)sum of masses of two positrons and two neutrons
d)      Two positrons as each positron carries a single positive charge   Ans: (b)


KINETIC THEORY OF MATTER:
1)      Regarding the atom  of a chemical element, the magnetic quantum number refers to     (2003)
a)      Orientation  b) shape  c) size    d) spin          Ans: ( a )



NATURE OF MATTER:
1)      Which one of the following present  in the largest amount in terms of percent by mass in the earth’s crust?                                                                                                                          (1997)
a)      Silicon  b) Oxygen  c) Carbon   d) Calcium       Ans: Oxygen  (upto 46.8%)
2)      One mole of hydrogen gas burns in excess of oxygen to give 290 kJ of heat. What is the      (1994)
Amount of heat produced when 4 g of hydrogen gas is burnt under the same conditions?
a)145 kJ   b) 290 kJ   c) 580 kJ    d) 1160 kJ        Ans:  ( c )
3) If a gas is compressed to half of its original volume at 27 degrees C, to what temperature should it be heated to make it occupy its original volume ?                                                                                                         (1994)
a) 327° C   b) 600° C    c) 54° C    d) 300° C          Ans: (a )

PERIODIC TABLE OF ELEMENTS:
1)      The most reactive among the halogens is                                         ( 1997)
a)      Fluorine  b) chlorine  c) bromine  d) iodine     Ans: ( a )
2)Consider the following statements with reference to the Periodic Table of chemical elements: (2001)
    1. Ionisation potential gradually decreases along a period
    2. In a group of elements, electron affinity decreases as the atomic weight increases
    3. In a given period, electronegativity decreases as the atomic number increases
   Which of these statement is / are correct ?
a)      1 only   b) 2  only   c)  1 and 3    d) 2 and 3          Ans:    b) 2  only

2)      In the periodic table of chemical elements, electron affinity is always found to increase from top to bottom in a group.   What is atomic radii ?                                   ( 2003 )
a)      Is the distance from centre of nucleus of an atom to the outmost shell of electron
b)      It is electrons
c)       It is neutrons
d)      It  is protons                                              Ans : a  


RADIO ACTIVITY :
1)      Which one of the following is not radioactive ?                                    (2001)
a)      Astatine  b) Francium  c) Tritium  d) Zirconium        Ans: d

2)      The half-life of a radioactive element is 5 years. The fraction of the radioactive substance that remains after 20 years is                                                                           ( 1994)
a)      ½      b) ¾       c) ⅛        d) ⅟16                                       Ans: d



TYPES OF CHEMICAL SOLUTIONS

1)Which one of the following statements is not correct?   (2002)
a) The boiling point of an aqueous solution is higher than that of pure water
b) Addition of solutes to a solution causes an increase in its water potential
c) The vapour pressure of the water in a solution is lower than that of pure water
d) When a solution is separated from water by a semipermeable membrane, water movement can be prevented by applying pressure to the solution                                                             Ans : (b)

2) Soft drinks such as colas contain significant quantities of   (2002, 2000)
a) Caffeine    b) Nicotine   c) Tannin    d) Resin                                                      Ans : (d)

3) Consider the following statements:      (2000)
Hard water is not suitable for
1)      Drinking           2) Washing clothes with soap
3)Use of boilers     4) Irrigating crops
Which of these statements are correct?   
a)       1 and 3       b) 2 and 3
c)1,2 and 4      d) 1,2,3 and 4                                                                                 Ans: (d)

4) Water is a good solvent of ionic salts because   (1994)
a) It has a high boilng point
b) It has a high dipole m ovment
c) It has a high specific heat
d) It has no colour                                                                                                            Ans : (b

5) Which one of the following colloidal systems is represented by fog?    (1993)
a) liquid in gas
b) Gas in liquid
c) solid in gas
d) Liquid in liquid                                                                                                              Ans: (b)



INORGANIC CHEMISTRY
1)      Which one of the following materials is very hard and very ductile?                          (2000)
a)      Carborundum   b) Tungsten  c) Cast Iron   d) Nichrome
Ans: (d)
2)      A: Sodium metal is stored under kerosene
R: Metallic sodium melts when exposed to air                    Ans:  ( c )                              (1998)
Explanation: When sodium is kept in air, it burns to form Na2  O  and Na2  O 2

3)      Consider the following statements about acetylene                                                        (1998)
1.       It is used in welding industry
2.       It is raw material for preparing plastics
3.       It is easily obtained by mixing silicon carbide and water
Of these statements:
a)      1 and 2 are correct    b) 1 and 3 are correct
c)2 and 3 are correct    d) 1,2 and 3 are correct           Ans: (b)
4) Which one of the following elements is allowed with iron to produce steel which         (1996)
can resist high temperatures and also have high hardness and abrasion ‘resistance?
a)      Aluminium   b) Chronium  c) Nickel   d) Tungsten         Ans: (b)
5)Monozite is an ore of                                                                                                                                 (1994)
a) Zirconium    b) Thorium   c) Titanium   d) Iron                        Ans : (b)
6) Galvanised iron sheets are protected from rusting due to the presence of a layer of       (1994)
the presence of a  layer of
a)      Lead     b) Chronium   c) Zinc  d) Tin             Ans (c )

7) Quartzite is metamorphosed from                                                                                                       (1994)
a) Limestone   b) Obsidian     c) Sandstone     d) Shale          Ans : ( c )




ELECTRO CHEMISTRY
1)      Aluminium  surface are often ‘anodized’ . This means the deposition of a layer of     (2000)
a)      Chromium oxide    b)Aluminium oxide  c) Nickel oxide    d) Zinc oxide        Ans: (b)
2)      Which one of the following metals does not form amalgams ?                                         (1998)
a)      Zinc   b) Copper   c) Magnesium  d) Iron                                                               Ans: (b)
3)      Which one of the following pairs of materials serves as electrodes in chargeable batteries commonly used in devices such as torchlight, electric shavers etc?                   ( 1995)
a)      Nickel and cadmium  b) zinc and carbon  c) lead peroxide and lead   d) iron and cadmium  Ans:(a)





DETERGENTS AND SOAPS

1)      Consider the following statements:                                                                                         (2003)
The purpose of adding sodium sulphate and sodium silicate to the detergent in a washing powder is
a)      To keep the washing powder dry
b)      To maintain the alkalinity of the powder                                               Ans : a

2)      Synthetic detergents can leather well in which water?
Ans : Well water                                                                                                                               (2002)




ACIDS AND BASES


1)      An aqueous solution of copper sulphate is acidic in nature because the salt undergoes
a)      Dialysis    b) electrolysis   c) hydrolysis   d) photolysis                                    (2001)
Ans: c
2)      When ants bite, they inject
a)      Glacial acetic acid   b) methanol    c) formic acid      d) stearic acid           ( 1999)
Ans: c
3)      Glass can be etched or scratched by
a)      Diamond    b) hydrofluoric acid   c) aquaregia  d) conc.sulpuric acid          (1999)
   Ans: diamond used for cutting  and hydrofluoric acid for writing on the glass
4)      To dilute sulphuric acid, ____ is added to the water and not water to acid        ( 1999)
          Ans:    acid

5)      Formic acid is a _______ acid than  acetic  acid                                                                   (1999)
Ans: stronger
6)      Acid precipitation is now regarded as a serious problem in some European            (1998)
and Asian countries. Its major cause or source is
a)      Discharge of acidic effluents onto neutral or slightly alkaline land where the acidic components precipitate
b)      Emissions of sulphur oxides and nitrogen oxides from thermal powder plants and burning of fossile fuels; these oxides dissolve in atmospheric water vapour and fall back on earth as acid rain
c)       Naural carbondioxide released during respiration of living oranisms dissolves in water, forming carbonic acid which is the chief contributor to acidity in rain water
d)      Chlorofluorocarbons readily react with various chemicals near the earth’s surface, producing acidic intermediates which cause acid precipitation                Ans¨(b)
7)      Vinegar is an aquerous solution of                                                                                           ( 1993)
a)      Oxalic acid   b) citric acid    c) acetic acid    d) hydrochloric acid          Ans: c



INDUSTRIAL CHEMISTRY
1)Coal based thermal power stations contribute to acid rain because  ______ are emitted when coal burns.
a) oxides of carbon                                                         Ans: a                                                                    ( 2003)

2)Most of the explosions in mines occur, due to the mixing of                                                    ( 2000)
a) hydrogen with oxygen    b) oxygen with acetylene   c) methane with air           
d) carbon dioxide with ethane                                                                   Ans: c

3)Phenyl is used as a household  ________                                                                                        (1998)
 a) germicide                                                                                                      Ans: a




METALLURGY
1)      Match the following :
(2000)
  Industrial Process                                                                          Industry with which associated
A.      Cracking                                                                               1. Rubber
B.      Smelting                                                                              2. Petroleum
C.      Hydrogenation                                                                  3. Copper
D.      Vulcanization                                                                     4. Edible Fats
Ans:  A:2,       B:3,      C:4,      D:1

2)      Consider the following statements:                                                                               (1998)
Coke is one of the materials of the charge added to blast furnace for the production of steel/iron. Its function is to
1.       Act as the reducing agent
2.       Remove silica associated with the iron ore
3.       Function as fuel, to supply heat
4.       Act as an oxidizing agent
Of these statements which are correct:
a)      1 and 2    b)   2 and 4    c) 1 and 3    d)  3 and 4                                Ans : c








ORGANIC CHEMISTRY

HYDROCARBONS:-
1)      Which one of the following is the correct sequence in increasing order of molecular weights of the hydrocarbons ?         (2001)
a)      Methane, ethane, propane and butane
b)      Propane, butane, ethane and methane
c)       Butane , ethane, propane and methane
d)      Butane, propane, ethane and methane
Ans: (a)

2)      Which one of the following types of coal contains a higher percentage of carbon than the rest ? (1999)
a)      Bituminuous coal   b) Lignite   c) Peat    d) Anthracite        Ans: (d)  Anthracite
3)Which one of the following has the highest fuel value?            (1997)
a) Hydrogen  b) Charcol  c) Natural gas    d) Gasoline            Ans : (a) Hydrogen







BIO-CHEMISTRY

ENVIRONMENTAL CHEMISTRY AND POLLUTION
1)      Which one of the following is produced during the formation of photochemical smog?   (2003)
a)      Hydrocarbons b) Nitrogen Oxides  c) Ozone   d) ethane     Ans: (b) Nitrogen Oxides

2)      The water pollution in river is measured by dissolved amount of ______       (1998)
a)      Chlorine  b) Ozone   c) Nitrogen   d) Oxygen            Ans:    (d)       Oxygen
3)      Which one of the following fuels causes minimum environmental pollution?       ( 1995)
a)      Diesel  b) Coal   c) Hydrogen   d) Kerosene          Ans: ( c )   Hydrogen
4)      The main constituents of peal are                                                                                            (1994)
a)      Calcium carbonate and magnesium carbonate
b)      Aragonite and conchiolin
c)       Ammonium sulphate and sodium carbonate
d)      Calcium oxide and ammonium chloride          Ans: (a)
5)Which radioactive pollutant has recently drawn the attention of the public, due to its occurrence in the building material?            
a) Plutonium    b) Thorium  c) Radon       d) Radium             Ans: ( c )                                                        (1994)

5)      If water pollution continues at its present rate, it will eventually                                                ( 1994)
a) Stop water cycle    b) prevent precipitation   c) make oxygen molecules unavailable to water plants
d) make nitrate unavailable to water plants                          Ans: ( c )




ECOLONY AND ENVIRONMENT

1)Within biological communities, some species are important in determining the ability of a large number of other species to persist in the community. Such species are called as             (2000)
a) Keystone species   b) Allopatric species   c) Sympatric species   d) Threatened species      Ans: a

2)Which one of the following organisms is likely to show the highest concentration of DDT once it has been introduced into the ecosystem ?                                                                                     (1997)
a) Grasshopper    b) Toad   c) Snake   d) Cattle                               Ans : c

3)The only anthropoid ape to be found in India is the                                                        (1994)
a) Hanuman monkey  b) Lion tailed macaque of Western Ghats
c)Slow Loris of Assam   d) White brewed gibbon of Assom              Ans: d

4)Biofilms are                                                                                                                                                    (1993)
a) colour films used by biologists to photograph living organisms
b) Photomicrographs of micro-organisms from various habitats
c) accumulation of micro-organisms  at surfaces such as those of a rock, a tooth or an oil droplet
d) Photographic films made through fermentation processes of certain industrial microorganisms   Ans:c

5)Which one of the following provides the best estimate of the world’s biological diversity?        (1993)
a) Of about ten million species probably alive today, some 20 species are lost everyday, most of them unknown because no more than half a million have, yet been actually identified by sientists
b)Of about thirty million living species, some 50 are lost every day, most of them unknown because no more than half a million have yet been actually identified by scientists
c)Of about forty five million living species, some 100 are lost everyday, most of them unknown because no more than 1.5 million have been actually identified
d)Of about seventy five million living species, some 500 are lost everyday, most of them unknown because no more than 3 million have been actually identified            Ans:  (d)

6)Which one of the following strongly threatens biodiversity?                                     (1993)
a) Fragile ecosystems such as mangroves and wetlands
b)Inaccessible habitats in the Himalayas
c)Destruction of natural habitats, vegetation and shifting cultivation
d) Creation of biosphere reserves                                                                            Ans: ( c )









FOOD CHEMISTRY
1)      Saturated fats have single bon in their structure.   Unsaturated fats can have double or more than double bonts which results in ______________ compared to saturated fats       ( 2003)
Ans:    very high reactivity
2)      Drinking of whisky increases the frequency of urination.    Alcohol intake speeds up the secretion of vasopressin in the body.           True / Untrue                                                                        (2002)
Ans:  True
3)      Which one of the following is an active compound of oil of clove?                             (1997)
a)      Menthol  b) Eugenol  c) methanol   d) Benzaldehyde      Ans: (b)
4)      The characteristic odour of garlic is due to                                                                            ( 1997)
a)      A chloro compound  b) a sulphur compound
c) A fluorine compound   d) acetic acid                         Ans: (b)

5)      Which of the following elements are present in all proteins?                                       (1995)
a)      Carbon  b) Hydrogen  c) Oxygen   d) Nitrogen       Ans: All  the above
6)        Consumption of fish is considered to be healthy when compared to flesh of other animals because fish contains?                                                                                                                             (1995)
a)      Polyunsaturated fatty acids   b) saturated fatty acids
c)Essential vitamins   d) more carbohydrates and proteins      Ans: (a)

AGRICULTURE CHEMISTRY:
1)      Which one of the following is a mixed fertilizer ?                                                               (1995)
a)Urea   b) CAM    c) Ammonium sulphate   d) NPK     Ans: d   Nitrogen,Phosphorous,Potassium

POLYMERS AND PLASTICS:
1)      Which one of the following polymers is widely used for making bullet proof material?    (1995)
a)      Poly vinyl chloride   b) polyamides  c) polyethylene  d) polycarbonates   Ans: (b)



BIOCHEMISTRY AND LIFE PROCESS:
1)The major chemical compound found in human kidney stone is                          (1998, 2000)
a)Uric acid   b) calcium carbonate  c) calcium oxalate  d) calcium sulphate     Ans: ( c )

2)Which of the following professional(s) are more likely to run the risk of a permanent change in their cell’s DNA?                                                                                                                                                (1996)
      1) Researchers using carbon-14 isotope    2) X-ray technicians
      3) Coal miner    4) Dyer and painter
Code:
a)        2 alone     b) 1,2 and 3       c) 1,2 and 4      d) 1,3 and 4           Ans:   (b)




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